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Cement Uptake Mechanisms

Influence of the Inherent Heterogeneity of Cement on the Uptake Mechanisms of Ni and Co: A Micro-Spectroscopic Study

Language EnglishEnglish
Book Paperback
Book Cement Uptake Mechanisms Marika Vespa
Libristo code: 07138454
Cement-based materials are used worldwide for solidifying and stabilizing hazardous and radioactive... Full description
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Cement-based materials are used worldwide for solidifying and stabilizing hazardous and radioactive wastes in order to prevent or retard the release of contaminants from the waste matrix into the environment. The long-term disposal of cement-stabilized hazardous waste is associated with landfilling of these waste forms, whereas deep geological disposal is foreseen for some categories of cement-stabilized radioactive waste. For the latter waste form, cement is used to condition and stabilize the waste materials and to construct the engineered barrier systems. The uptake mechanism of Ni(II) and Co(II) by hardened cement paste at different reaction conditions were investigated by combining macro- and micro-spectroscopic techniques. The findings from this study indicate that, although Ni(II) and Co(II) are both divalent cations, they react differently during the hydration of cement. Nevertheless, both cations became immobilized in specific minerals phases. These immobilization processes are expected to reduce the mobility of Co and Ni in the cement matrix and, consequently the impact on the environment.

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About the book

Full name Cement Uptake Mechanisms
Author Marika Vespa
Language English
Binding Book - Paperback
Date of issue 2012
Number of pages 144
EAN 9783838135021
ISBN 3838135024
Libristo code 07138454
Weight 222
Dimensions 152 x 229 x 9
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