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Insights into Stimuli-Responsive Polymers

Name: Insights into Stimuli-Responsive Polymers
Brand: VDM Verlag
SKU: 06824924
Price: 59.98 EUR
Availability: InStock
Author: Alexei M. Kisselev
ISBN: 9783639165333

Alexei M. Kisselev

Language

English

Book Paperback

Libristo code: 06824924

Publishers VDM Verlag, July 2009

The phase behavior of temperature-responsive polymers§with tunable lower critical solution temperatu... Full description

Libristo code: 06824924

145 b

59.98 €

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The phase behavior of temperature-responsive polymers§with tunable lower critical solution temperatures§(LCST) and light-responsive polymers was explored§using statistical mechanics and molecular dynamics§simulations. §§The LCST in water of (ethylene oxide)/ethylene§copolymers is tailored by their§chemical composition. For the first time, the general§formalism of the§lattice-fluid with hydrogen-bonding (LFHB) theory has§been successfully applied to a water-polymer system.§This theory, modified here to account for§multiple types of hydrogen bonds, has been shown to§be effective when making theoretical§predictions as justified by comparison with§experimental results. The series of (ethylene§oxide)/ethylene copolymers were studied further with§the modified Flory-Huggins with hydrogen bonding§(FHHB) approach. §§Expanding beyond temperature-responsive polymer§solutions, systems that can potentially find§applications in antifouling, drug delivery, and§surfaces with switchable tackiness, the work§subsequently focused on a light-responsive polymer§film systems that have applications in photolithography.