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Photochemical Reactions Via Zwitterionic Intermediates

Name: Photochemical Reactions Via Zwitterionic Intermediates
Brand: Scholars' Press
SKU: 07085241
Price: 218.33 EUR
Availability: InStock
Author: Majher I. Sarker
ISBN: 9783639708783

Majher I. Sarker

Tasnuva Shahrin

Language

English

Book Paperback

Libristo code: 07085241

Publishers Scholars' Press, February 2014

The research focuses on the design of photoremovable protecting groups that can be used to deprotect... Full description

Libristo code: 07085241

532 b

218.33 €

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The research focuses on the design of photoremovable protecting groups that can be used to deprotect biological substrates of an organic compound by photolysis. The deprotection of the protecting group via photolysis requires heterolysis of a bond to the substrate. Heterolysis of a C-O or C-S -bonds in a zwitterionic intermediate is proposed. The photochemical electrocyclic reactions studied involve acrylanilides, benzothiophene carboxanilides, and N-(9-oxothioxanthenyl) benzothiophene carboxamides. The most efficient photochemical electrocyclic ring closure and leaving group expulsion found thus far occurs with benzothiophene carboxanilides, which has considerable potential for use as cage compounds.